Material of the Decade - Graphyne

Mr. McGuire: I just want to say one word to you,  Just one word.
Benjamin: Yes, sir.
Mr. McGuire: Are you listening?
Benjamin: Yes, I am.
Mr, McGuire: Graphyne.
Benjamin: Exactly how to you mean?

This is an example of the "how" associated with Graphyne - - from MIT Technology Review, How Carbon Wonder-Materials Are Promising To Revolutionise Desalination:

"Conventional desalination plants that rely on reverse osmosis require a massive 1.5 kiloWatt-hours of electricity to produce 1 tonne of freshwater. Clearly a better approach is needed.

Today, Wanlin Guo and friends at Nanjing University of Aeronautics and Astronautics in China say they have identified just such a better way. The new technique involves a material known as graphyne, a two-dimensional sheet of carbon atoms connected together much like graphene but with an altered structure because of double and triple bonds in certain places.

Graphyne is interesting because these double and triple bonds create holes between the carbon atoms that are large enough for water molecules to pass through. However, these holes are not big enough for sodium and chloride ions, which are larger because they attract a shell of water molecules since they are charged.

Graphyne can form in several configurations known as α-graphyne, β-graphyne, graphyne-3 and so on. Wanlin and co have created a computer simulation of the way that these membranes allow water molecules to pass through while sieving the various types of ions found in seawater.

Their conclusions are promising. They say that while water molecules can move freely back and forth through the holes in graphyne, none of the ions they simulated could pass through at all.

According to their calculations, a water molecule has to cross an energy barrier of less than 2 kcal/mol to pass through graphyne. By contrast, the energy barriers opposing the passage of sodium, potassium and chloride ions are in the region of 10 kcal/mol. And doubly charged ions such as magnesium and calcium face energy barriers as high as 60 kcal/mol.

“None of these ions can permeate through α-graphyne, β-graphyne and graphyne-3,” they say.
What’s more, Wanlin and co say that water passes through graphyne at a rate some two orders of magnitude faster than through the polymer membranes used in conventional reverse osmosis techniques.

There’s a caveat, of course. Nobody has ever been able to make graphyne of the type that these guys have simulated.

That may change in the near future. A couple of years ago, a team of Chinese chemists grew a different version of graphyne on a copper substrate, the first time that any type of graphyne had been synthesised.

So an important question is first whether this membrane material can actually be synthesised and whether it can be done on an industrial cost-effective scale. That’s no small challenge.
In the meantime, desalination is set to improve thanks to another carbon wonder material. Earlier this year, researchers from the aerospace giant Lockheed Martin announced that they had punched holes in sheets of graphene to produce a molecular sieve that removes sodium and chloride ions from seawater. This, they said, could desalinated seawater much more quickly and cheaply than existing methods."